Runaway rection of a non-stabilised chlorinated hydrocarbon with aluminium (enlarged picture)
During the degreasing process of aluminium or aluminium alloy with non-stabilised CHC exothermic polycondensation reactions under dechlorination of the CHC can be initiated. To avoid this exothermic reaction stabilised chlorinated hydrocarbons are used.
BAM offers a self-developed examination method that determines both the stability of the stabilised original CHC and the stability of chlorinated hydrocarbons recycled by destillation. The recycled solvents may be reused for degreasing aluminium or aluminium alloys under controlled reprocessing treatment.
| Apparatus | Three-necked-flask, reflux condenser, tempering bath |
|---|---|
| Sample | 100 ml fresh CHC or distilled CHC |
| Aluminium component | Al (thin leaves with defined dimension) and aluminium chloride |
| Simulation of organic contamination by | zinc stearate or oleic acid |
| Test procedure |
18 h under reflux conditions respectively up to the start of the exothermic reaction
|
BAM Equipment and facilities | Chemical Process Safety
Division 2.2
Reactive Substances
and Systems